A study of water exchange in wood by means of 2D NMR relaxation correlation and exchange

نویسندگان

  • Julia Cox
  • Peter J. McDonald
  • Barry A. Gardiner
چکیده

Two-dimensional T1-T2 H NMR relaxation correlation spectra and T2-T2 relaxation exchange spectra for samples of spruce wood across the full moisture content range from 0% to )100% are presented. The T1-T2 spectra unambiguously identify water in different environments within the wood that overlap in the corresponding and more traditional one-dimensional T1 or T2 experiment. The T2-T2 spectra unambiguously reveal the presence of water exchange between the lumen and cell wall above the fibre saturation point in sapwood. An estimate is made of the exchange rate: 1/30 to 1/3 ms.

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تاریخ انتشار 2010